HIx system thermodynamic model for hydrogen production by the Sulfur–Iodine cycle |
| |
Authors: | Mohamed Kamel Hadj-Kali Vincent Gerbaud Jean-Marc Borgard Olivier Baudouin Pascal Floquet Xavier Joulia Philippe Carles |
| |
Affiliation: | 1. Université de Toulouse, INP, UPS, LGC (Laboratoire de Génie Chimique), 5 rue Paulin Talabot, F-31106 Toulouse Cedex 01, France;2. CNRS, LGC (Laboratoire de Génie Chimique), F-31106 Toulouse Cedex 01, France;3. CEA, DEN, Physical Chemistry Department, F-91191 Gif-sur-Yvette, France;4. ProSim, Stratège Bâtiment A, BP 27210, F-31672 Labège Cedex, France |
| |
Abstract: | The HIx ternary system (H2O–HI–I2) is the latent source of hydrogen for the Sulfur–Iodine thermo-chemical cycle. After analysis of the literature data and models, a homogeneous approach with the Peng–Robinson equation of state used for both the vapor and liquid phase fugacity calculations is proposed for the first time to describe the phase equilibrium of this system. The MHV2 mixing rule is used, with UNIQUAC activity coefficient model combined with of hydrogen iodide solvation by water. This approach is theoretically consistent for HIx separation processes operating above HI critical temperature. Model estimation is done on selected literature vapor–liquid, liquid–liquid, vapor–liquid–liquid and solid–liquid equilibrium data for the ternary system and the three binaries subsystems. Validation is done on the remaining literature data. Results agree well with the published data, but more experimental effort is needed to improve modeling of the HIx system. |
| |
Keywords: | Sulfur&ndash Iodine cycle HIx system Phase equilibrium modeling Complex mixing rule |
本文献已被 ScienceDirect 等数据库收录! |
|