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A 3D 3d-4f Heterometallic Coordination Polymer: Synthesis,Crystal Structure and Properties
Authors:Guang-Xiang Liu  Yan Wang  Liang-Fang Huang  Xue-Jun Kong  Hong Chen
Affiliation:(1) Anhui Key Laboratory of Functional Coordination Compounds, College of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, 246003, People’s Republic of China
Abstract:Abstract  A three-dimensional heterometallic coordination polymer formulated as Sm2Zn2(BIPA)5(H2O)2 (1) (H2BIPA = 5-bromoisophthalic acid) was synthesized by hydrothermal reaction of H2BIPA with Sm2O3 and Zn(NO3)2. Complex 1 shows an 8-connected (36.418.53.6) topological network. The thermal analysis of complex 1 has been measured and discussed. Additionally, the photoluminescent property of complex 1 was investigated. Graphical Abstract  An intriguing feature of complex 1 is a 3D eight-connected framework of 36.418.53.6 topology. MediaObjects/10904_2008_9212_Figa_HTML.gif
Keywords:X-ray diffraction  Carboxylate ligand  Heterometallic coordination polymer  Photoluminescent property
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