A 3D 3d-4f Heterometallic Coordination Polymer: Synthesis,Crystal Structure and Properties |
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Authors: | Guang-Xiang Liu Yan Wang Liang-Fang Huang Xue-Jun Kong Hong Chen |
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Affiliation: | (1) Anhui Key Laboratory of Functional Coordination Compounds, College of Chemistry and Chemical Engineering, Anqing Normal University, Anqing, 246003, People’s Republic of China |
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Abstract: | Abstract A three-dimensional heterometallic coordination polymer formulated as Sm2Zn2(BIPA)5(H2O)2 (1) (H2BIPA = 5-bromoisophthalic acid) was synthesized by hydrothermal reaction of H2BIPA with Sm2O3 and Zn(NO3)2. Complex 1 shows an 8-connected (36.418.53.6) topological network. The thermal analysis of complex 1 has been measured and discussed. Additionally, the photoluminescent property of complex 1 was investigated.
Graphical Abstract An intriguing feature of complex 1 is a 3D eight-connected framework of 36.418.53.6 topology.
![MediaObjects/10904_2008_9212_Figa_HTML.gif](/content/868u870l3770n5vp/MediaObjects/10904_2008_9212_Figa_HTML.gif) |
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Keywords: | X-ray diffraction Carboxylate ligand Heterometallic coordination polymer Photoluminescent property |
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