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| 漆酶/介体体系改性磨石磨木浆纤维表面性能分析 | |
| 引用本文： | 张爱萍,秦梦华,徐清华,孙润仓. 漆酶/介体体系改性磨石磨木浆纤维表面性能分析[J]. 中国造纸学报, 2007, 22(3): 21-25 |
| 作者姓名： | 张爱萍 秦梦华 徐清华 孙润仓 |
| 作者单位： | 1. 山东轻工业学院制浆造纸工程省级重点学科,山东济南,250100;华南理工大学制浆造纸工程国家重点实验室,广东广州,510640 2. 山东轻工业学院制浆造纸工程省级重点学科,山东济南,250100;中科院广州化学研究所纤维素重点实验室,广东广州,510650 3. 山东轻工业学院制浆造纸工程省级重点学科,山东济南,250100 4. 华南理工大学制浆造纸工程国家重点实验室,广东广州,510640 |
| 摘 要： | 利用漆酶价体体系改性未漂马尾松磨石磨木浆，测定改性前后浆张的物理和光学性能，利用纤维长度、粗度分析仪、傅里叶变换红外光谱（FT-IR）和化学分析光电子能谱（ESCA）对漆酶价体体系改性前后纸浆纤维变化及表面性能进行分析，并测定了纸浆表面接触角（CA）。结果表明，漆酶价体体系改性纸浆仅在纤维的表面起作用，不会引起纤维的大幅度降解；纸浆改性过程中发生了氧化反应，羰基含量增加；改性后木素发生了一定程度的降解，纸浆表面木素含量降低；改性后的纸浆表面润湿性能提高。 |
| 关 键 词： | 漆酶/介体体系 磨石磨木浆 表面分析 |
| 文章编号： | 1000-6842（2007）03-0021-05 |
| 修稿时间： | 2007-03-02 |
Surface Properties of Masson Pine Stone Groundwood Pulp Modified by Laccase/Mediator System |
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| ZHANG Ai-ping,QIN Meng-hua,XU Qing-hua,SUN Run-cang. Surface Properties of Masson Pine Stone Groundwood Pulp Modified by Laccase/Mediator System[J]. Transactions of China Pulp and Paper, 2007, 22(3): 21-25 | |
| Authors: | ZHANG Ai-ping QIN Meng-hua XU Qing-hua SUN Run-cang |
| Abstract: | Modification of Masson pine stone groundwood pulp with laccase/mediator system was studied in this paper. Surface properties of modified pulps were studied by ATR-IR, ESCA and the contact angle of the pulp was measured.The average length and coarseness of LMS modified fibers changed little compared with the control. The measurement of fiber contact angle showed that hydrophilicity of the modified pulp was higher than that of the control. ATR-IR analysis showed that new carbonyl groups were formed during LMS treatment. ESCA analysis showed that O/C was higher than that of the control, and the surface lignin content decreased after LMS treatment. |
| Keywords: | laccase/mediator system stone groundwood pulp surface properties |
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