多相流动状态下温度对X70钢CO2腐蚀的影响

目的提高多相流动状态下温度对X70钢CO2腐蚀机理的认识。方法采用自制实验装置和挂片实验,模拟起伏管路段塞流动条件下X70钢的CO2腐蚀状态,通过电子显微镜和电化学在线监测等手段对试样表面形貌、腐蚀速率以及在线腐蚀情况进行观察和分析,侧重研究多相流动状态下温度对X70钢CO2腐蚀速率的影响。结果当温度达到90~98℃时,由于腐蚀产物膜的影响,CO2分压对腐蚀速度影响甚微,腐蚀速度降至较低水平。当温度在60~80℃之间时,腐蚀挂片表面的腐蚀状态不稳定,出现局部腐蚀或均匀腐蚀,当CO2分压较低时(如0.15 MPa),易形成均匀腐蚀;当CO2分压较高时(如0.6 MPa),易形成局部腐蚀。当温度在40~80℃之间时,随着CO2分压的增加,腐蚀速率达到最高值的温度越来越高,腐蚀速率达到最高值的温度范围一般保持在40~80℃之间。结论温度对X70钢CO2腐蚀的影响与CO2分压密切相关,相同温度下,随着CO2分压的增加,腐蚀速率增大,相应的腐蚀速率达到最高值的温度也越来越高;孤立地说某一温度值下,CO2腐蚀速率达到最高值这一说法不准确。

Effects of temperature on the CO2 corrosion of the X70 steel under multiphase flow environments

ABSTRACT:Objective To improve the understanding of CO2 corrosion mechanism at different temperature under multiphase flow condition. Methods The CO2 corrosion status of X70 steel under the condition of plug flow was simulated using the self-made ex-perimental device and the hanging plate experiment. The surface morphology, corrosion rate and online coupon corrosion situation were observed and analyzed by electron microscopy and electrochemical monitoring. The effect of temperature on the CO2 corrosion rate of X70 steel was focused on. Results The CO2 partial pressure had little effect on the corrosion rate, and the corrosion rate de-creased to a lower level when the temperature reached 90~98℃, due to the influence of corrosion product film;when the temper-ature was in the range of 60~80 ℃, the corrosion status of the hanging plate surface was not stable, and partial corrosion or uni-form corrosion occurred, which depended on the CO2 partial pressure. When the CO2 partial pressure was low, such as 0. 15 MPa, it was easy to form uniform corrosion, and when the CO2 partial pressure was high, such as 0. 6 MPa, it was easy to form partial corrosion. when the temperature was in the range of 40~80 ℃, the temperature at which the corrosion rate reached its maximum increased with increasing CO2 partial pressure, and the temperature range generally remained between 40~80 ℃ when the corro-sion rate reached its maximum. Conclusion The effect of temperature on the CO2 corrosion of X70 steel was closely related to the partial pressure of CO2 . At the same temperature, the corrosion rate increased with the increase of CO2 partial pressure, and the temperature of the corresponding maximum corrosion rate also increased. It was not accurate to say that the CO2 corrosion rate reached the highest at a certain temperature.