| CuPc/Y分子制备与性能的研究 |
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| 引用本文： | 范彬彬,李瑞丰,樊卫斌,曹景慧,钟炳.CuPc/Y分子制备与性能的研究[J].石油学报(石油加工),2000,16(1):12-16. |
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| 作者姓名： | 范彬彬 李瑞丰 樊卫斌 曹景慧 钟炳 |
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| 作者单位： | [1]太原理工大学精细化工研究所 [2]中国科学院山西煤炭化学研究所 |
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| 摘 要： | 用固体凝胶法制备了ＣｕＰｃ／Ｙ分子筛，考究了合成条件对制备的影响。用ＩＣＰ，ＴＧ－ＤＴＡ，ＳＥＭ，ＦＴ－ＩＲ，ＵＶ－ＶＩＳ及催化反应等对其性能了表征。结果表明，在无定形硅铝凝胶中，铜酞菁经过水热晶化后，８５％的金属配合物被封装在Ｙ型分子筛的超笼中，高于文献所报道的数值。
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| 关 键 词： | 铜酞菁 分子筛 环己烷 氧化反应 固体凝胶法 |
STUDIES ON PREPARATION AND CHARACTERISTICS OF CUPC/Y ZEOLITES |
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| FAN Bin-bin,LI Rui-feng,FAN Wei-bin,CAO Jing-hui,ZHonG Bing.STUDIES ON PREPARATION AND CHARACTERISTICS OF CUPC/Y ZEOLITES[J].Acta Petrolei Sinica (Petroleum Processing Section),2000,16(1):12-16. |
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| Authors: | FAN Bin-bin LI Rui-feng FAN Wei-bin CAO Jing-hui ZHonG Bing |
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| Abstract: | CuPc/Y zeolite was prepared by using solid gel, CuPc being encapsulated into supercages of zeolite Y Effects of crystallization conditions of zeolite Y synthesized on CuPc/Y characteristics were investigated CuPc/Y zeolite was characterized by ICP, TG DTA, SEM, FT IR, UV VIS and catalytic oxidation of cyclohexane in the presence of hydrogen peroxide The results show that 85% of copper complex in amorphous silica alumina gel can be encapsulated in NaY supercages after hydrothermal crystallization CuPc encapsulated in zeolite NaY has higher catalytic activity in cyclohexane oxidation than the neat CuPc |
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| Keywords: | CuPc zeolite cyclohexane oxidation reaction |
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