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The formation of Co2C species in activated carbon supported cobalt-based catalysts and its impact on Fischer–Tropsch reaction
Authors:Jianmin Xiong  Yunjie Ding  Tao Wang  Li Yan  Weimiao Chen  Hejun Zhu  Yuan Lu
Affiliation:(1) Natural Gas Utilization and Applied Catalysis Laboratory, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China;(2) State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China
Abstract:The cobalt carbide (Co2C) species was formed in some activated carbon supported cobalt-based (Co/AC) catalysts during the activation of catalysts. It was found that the activity of Fischer–Tropsch reaction over Co-based catalysts decreased due to the formation of cobalt carbide species. Some promoters and pretreatment of activated carbon with steam could restrain the formation of cobalt carbide.
Keywords:cobalt carbide species  Fischer–  Tropsch synthesis  cobalt-based catalysts  activated carbon
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