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埕北稠油催化改质降粘实验研究
引用本文:崔盈贤,李晶晶,何柏,唐晓东,杨光.埕北稠油催化改质降粘实验研究[J].工业催化,2013,21(2):44-47.
作者姓名:崔盈贤  李晶晶  何柏  唐晓东  杨光
作者单位:1.海洋石油高效开发国家重点实验室,北京 100027; 2.中海油研究总院,北京 100027;; 3.西南石油大学化学化工学院,四川 成 都610500; 4.重庆科技学院化学化工学院,重庆 401331
基金项目:国家科技重大专项"海上稠油热采技术"
摘    要:室内评价埕北稠油催化改质降粘的实验效果,筛选出最优改质降粘催化剂,考察催化剂用量、反应温度、反应时间、供氢剂种类及用量对稠油改质降粘的影响。结果表明,采用有机酸锰催化剂和甲苯供氢剂,在催化剂用量为稠油质量的0.10%、反应温度240 ℃、反应时间24 h、水油质量比1∶3和甲苯用量为稠油质量的5%条件下,稠油粘度由2 740 mPa·s降至780 mPa·s,改质降粘率达到71.5%。

关 键 词:能源化学  埕北稠油  催化改质  降粘  

Experimental research on viscosity reduction of offshore heavy oil by catalytic upgrading
CUI Yingxian , LI Jingjing , HE Bai , TANG Xiaodong , YANG Guang.Experimental research on viscosity reduction of offshore heavy oil by catalytic upgrading[J].Industrial Catalysis,2013,21(2):44-47.
Authors:CUI Yingxian  LI Jingjing  HE Bai  TANG Xiaodong  YANG Guang
Affiliation:1.State Key Laboratory of Offshore Oil Exploitation, Beijing 100027, China; 2.CNOOC Research Institute, Beijing 100027, China; 3.School of Chemistry and Chemical Engineering, Southwest Petroleum University, Chengdu 610500, Sichuan, China; 4.School of Chemistry and Chemical Engineering, Chongqing University of Science and Technology, Chongqing 401331, Chin
Abstract:ndoor experiments on viscosity reduction of offshore heavy oil by catalytic upgrading were carried out in order to screen out the optimal upgrading catalyst.The influence of catalyst dosage, reaction temperature,reaction time,and the types and dosage of hydrogen donor was investigated.The results showed that using manganese organic acid as the catalyst and toluene as the hydrogen donor,the viscosity of cracked heavy oil decreased from 2 740 mPa·s to 780 mPa·s and the viscosity-reducing rate of 71.5% was attained under the optimum condition as follows:catalyst dosage 0.10%,reaction temperature 240 ℃,reaction time 24 h,water/oil mass ratio 1∶3,and hydrogen donor toluene dosage 5%.
Keywords:energy chemistry  offshore heavy oil  catalytic upgrading、 viscosity-reduction  
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