Spin trapping study on addition reaction of organic radicals to methyl methacrylate and methyl tiglate |
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Authors: | Mikiharu Kamachi Yoko Kuwae Shun -ichi Nozakura |
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Affiliation: | (1) Department of Macromolecular Science, Faculty of Science, Osaka University, Toyonaka, 560 Osaka, Japan |
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Abstract: | Summary The addition reaction of the radicals formed from 2,2zobisisobutyronitrile(AIBN), diisopropyloxydicarbonate(DISOP), or benzoyl peroxide(BPO) to methyl methacrylate--d2(MMA--d2) or methyl tiglate(MTA) has been investigated at 30°C by the spin trapping technique. The tail and head addition of the radicals were detected for MMA--d2, and only the tail addition was observed for MTA. |
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