Spin trapping study on addition reaction of organic radicals to methyl methacrylate and methyl tiglate期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

Spin trapping study on addition reaction of organic radicals to methyl methacrylate and methyl tiglate

Authors:	Mikiharu Kamachi Yoko Kuwae Shun -ichi Nozakura

Affiliation:	(1) Department of Macromolecular Science, Faculty of Science, Osaka University, Toyonaka, 560 Osaka, Japan

Abstract:	Summary The addition reaction of the radicals formed from 2,2zobisisobutyronitrile(AIBN), diisopropyloxydicarbonate(DISOP), or benzoyl peroxide(BPO) to methyl methacrylate--d₂(MMA--d₂) or methyl tiglate(MTA) has been investigated at 30°C by the spin trapping technique. The tail and head addition of the radicals were detected for MMA--d₂, and only the tail addition was observed for MTA.

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