Synthesis,structural characterization,and photocatalytic activity of Bi‐based nanoparticles |
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Authors: | Adriana Nuñez‐Briones Luis García‐Cerda Joelis Rodríguez‐Hernández Miguel Aguilar‐González Bertha Puente‐Urbina Esmeralda Mendoza‐Mendoza |
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Affiliation: | 1. Departamento de Materiales Avanzados, Centro de Investigación en Química Aplicada, Saltillo, Coahuila, México;2. Unidad Saltillo, Centro de Investigación y de Estudios Avanzados del I.P.N., Ramos Arizpe, Coahuila, México |
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Abstract: | Bi‐based nanoparticles were successfully synthesized (500°C/2 h) following two intermediate‐temperature routes, Pechini and a combined method of mechanical milling/molten salts. Herein, α‐Bi2O3/Bi2O2CO3 heterostructures were identified. These types of heterostructures have shown advantages to improve the visible light responsive activity of Bi‐based nanoparticles to facilitate the separation of photogenerated electron‐hole pairs. By fixing the experimental parameters, the synthesis route and Ag contents showed to play a very important role in the phase composition of the Ag‐containing samples; the formation of Bi/Ag‐Bi2O3/Bi2O2CO3 and Ag/Ag‐Bi2O3/Bi2O2CO3 complex hybrid structures were revealed. The α‐Bi2O3/Bi2O2CO3 heterostructure prepared by combined method exhibited higher photocatalytic efficiency (66.84%) for degrading methylene blue (MB) depending on Bi2O2CO3 component proportion. For the Ag‐containing hybrid structures, the performance of their catalytic activity did not show an increase with respect to α‐Bi2O3/Bi2O2CO3. However, in these samples, the degradation efficiency was slightly enhanced with the efficient doping of Ag into the α‐Bi2O3 structure and the existence of Bi when the Pechini method was used. Also, a possible photocatalytic process for degrading MB is presented. |
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Keywords: | Ag‐doped Bi2O3 Bi‐based nanoparticles heterostructures synthesis visible light photocatalysis activity |
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