Fourier Thermal Analysis of the Eutectic Formed in Pb-Sn Alloys |
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Authors: | H Cruz M Ramírez-Argaez A Juarez A Garcia C González-Rivera |
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Affiliation: | (1) Departamento de Ingeniería Metalúrgica, Facultad de Química, UNAM, Av. Universidad 3000 Cd. Universitaria 04510, México D.F., México;(2) Facultad de Ingeniería Mecánica y Eléctrica, Universidad Autónoma de Nuevo León, Pedro de Alba s/n, Ciudad Universitaria, San Nicolás de los Garza, Nuevo León, C.P. 66450, México |
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Abstract: | The effect of the presence of two different primary phases on the microstructural characteristics and solidification kinetics
of Pb-Sn eutectic was analyzed using Fourier thermal analysis method (FTA) and microstructural characterization. Three Pb-Sn
alloys, a hypoeutectic, an eutectic, and a hypereutectic alloy, were melted in an electric furnace under an argon atmosphere
and poured into sand molds. Cooling curves were obtained and numerically processed using FTA. Microstructural observations
of the probes indicate a lamellar morphology for the eutectic microconstituent of the hypereutectic alloy; the eutectic alloy
shows the presence of both lamellar and anomalous eutectic and the hypoeutectic alloy shows only the presence of anomalous
eutectic. FTA results indicate that in the case of the probes showing the presence of anomalous eutectic, there is a primary
eutectic formed during recalescence at high undercooling and a secondary eutectic yielded at low undercooling at the eutectic
plateau temperature. This result shows that the cause behind the observed differences in the eutectic morphologies of the
experimental alloys lies on the nucleating ability of the primary phase available as a potential substrate for nucleation
of the eutectic microconstituent. |
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Keywords: | anomalous eutectic Fourier thermal analysis Pb-Sn eutectic solidification kinetics |
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