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超临界CO2染色技术
引用本文:郑来久,刘志伟,季婷,姜涛,李安源,郭友才.超临界CO2染色技术[J].化学工程,2006,34(9):71-74.
作者姓名:郑来久  刘志伟  季婷  姜涛  李安源  郭友才
作者单位:大连轻工业学院,纺织轻工学院,辽宁,大连,116034;光明化工设计研究院,辽宁,大连,116031
基金项目:辽宁省科技厅科技攻关项目(2004223002),辽宁省教育厅科技攻关项目(2004D053),中国纺织工业总会资助项目(2004012)
摘    要:主要对超临界CO2染色技术进行了研究。运用超临界CO2特性,研制了无水染色装置,对该装置的基本结构及工作原理加以说明,并实现了计算机自动控制。使用无水染色装置,在超临界CO2状态下对纤维织物用分散染料进行染色,并采用扫描电镜和红外光谱仪测定分析改性和染色的效果。对染色工艺参数,如压强、温度和CO2的流量进行了分析,结果表明这些参数对染色效果影响较大。对天然纤维的改性,可以达到改善染色牢度和匀染度,通过合理控制染色压强、温度和CO2的流量等影响因素就可以取得较好的染色效果。

关 键 词:超临界CO2  染色装置  无水染色  纤维织物
文章编号:1005-9954(2006)09-0071-04

Technique of dyeing in supercritical CO2
ZHENG Lai-jiu,LIU Zhi-wei,JI Ting,JIANG Tao,LI An-yuan,Guo You-cai.Technique of dyeing in supercritical CO2[J].Chemical Engineering,2006,34(9):71-74.
Authors:ZHENG Lai-jiu  LIU Zhi-wei  JI Ting  JIANG Tao  LI An-yuan  Guo You-cai
Abstract:The technique for dyeing in supercritical CO_2 was studied.The water-free dyeing facility with automatic computer control was designed based on supercritical CO_2 characteristics.The basic structure and operating principle of the facility were elucidated.The fabrics were dyed with disperse dyeing under supercritical CO_2,and the results of modifying and dyeing were measured by electronic scanning microscopy and infrared spectrometric analyzer.The dyeing parameters such as pressure,temperature and CO_2 flux were analyzed,which influenced the dyeing to a large extent.The modification on fabrics improves the rate of dye-uptake and the degree of homogeneity.The better dyeing effect can be achieved by controlling reasonably the dyeing pressure,temperature and CO_2 flux.
Keywords:supercritical CO_2  dyeing facility  water-free dyeing  fabrics
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