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Electron field emission from the carbon-doped TiO2 nanotube arrays
Authors:Lin-Qing WangCheng-Wei Wang  Jian-Biao ChenRui-Sheng Guo  Feng ZhouWei-Min Liu
Affiliation:
  • a Key Laboratory of Atomic and Molecular Physics & Functional Materials of Gansu Province, College of Physics and Electronic Engineering, Northwest Normal University, Lanzhou 730070, China
  • b State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Science, Lanzhou 730000, China
  • Abstract:The field-emission characteristics of the carbon-doped TiO2 nanotube arrays (TNAs), which can be obtained by a heat treatment of the as-fabricated TNAs under a continuous argon and acetylene flux, were investigated. The morphology, crystalline structure, and composition of the as-grown specimens were characterized by the use of field-emission scanning electron microscopy (FE-SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), respectively. It was found that the samples' turn-on electric field is reduced from 21.9 to 5.0 V/μm and the field-emission current density rapidly reaches about 9.0 mA/cm2 at 11.8 V/μm after carbon doping. The dramatically improved field-emission characteristics would be mainly attributed to the reduced work function and the enhanced conductivity due to the carbon doping into TNAs.
    Keywords:Field emission   Titanium dioxide   Nanotube arrays   Carbon   Doping   Anodization
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