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用聚3,4-乙撑二氧噻吩对聚丙烯腈进行导电改性的研究
引用本文:夏友谊.用聚3,4-乙撑二氧噻吩对聚丙烯腈进行导电改性的研究[J].合成纤维,2008,37(9).
作者姓名:夏友谊
作者单位:安徽工业大学,化学与化工学院高分子科学与工程系,安徽,马鞍山,243002
摘    要:采用原位化学氧化聚合方法在聚丙烯腈纤维表面生成聚3,4-乙撑二氧噻吩,制备得到纤维表面均匀覆盖聚3,4-乙撑二氧噻吩的改性导电纤维,其电导率约为1×10-3S/cm。纤维表面与导电聚合物的相互作用改善了原纤维的耐热性能,并对其力学性能没有造成伤害。

关 键 词:聚丙烯腈  聚3  4-乙撑二氧噻吩  原位化学氧化聚合

Fabrication of Conductive Polyacrylonitrile Fibers Modified by Poly(3,4-ethylenedioxythiophene)
XIA You-yi.Fabrication of Conductive Polyacrylonitrile Fibers Modified by Poly(3,4-ethylenedioxythiophene)[J].Synthetic Fiber in China,2008,37(9).
Authors:XIA You-yi
Abstract:Conductive polyacrylonitrile fiber modified by poly(3,4-ethylenedioxythiophene) was fabricated successfully by in-situ chemical oxidation polymerization. The surface of polyacrylonitrile fiber was covered entirely and uniformly by conductive polymers. The novel composite fiber exhibited a conductivity of 1×10-3 S·cm-1, and still possessed former fibrillar morphologies and strength properties. In addition, improved thermal stability of the composite fiber was also observed.
Keywords:polyacrylonitrile  poly(3  4-ethylenedioxythiophene)  in-situ chemical oxidation polymerization
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