Stress corrosion cracking of carbon steel in caustic aluminate solutions—crack propagation studies

Stress corrosion cracking of a commercial 0.19 pct C steel (SA-516 Grade 70) was studied in hot (92 ‡C) caustic solutions of NaOH and NaOH plus aluminate (AlO⁻ ₂) species. Potentiostatically controlled tests were conducted near the active-passive transition, using fracture mechanics testing techniques and fatigue precracked double cantilever beam specimens. Crack propagation rates (Ν) were determined for a range of stress intensities (K _l). In simple NaOH solutions, Region I (K₁-dependent) and Region II (K ₁-independent) cracking behavior were observed. Increasing the concentration of NaOH from2m to8m decreasedK _ISCC and displaced Region I and the onset of Region II to lowerK ₁ levels. The presence of AlO⁻ ₂ produced a comparable effect, with Region II being extended to lowerK _I -Ν levels relative to simple NaOH solutions of similar hydroxyl anion concentration. The overallK _I -Νv behavior and fractography were consistent with a dissolution mechanism of crack advance based on the general principles of the film rupture-dissolution model. The effect of environment composition uponK _I — Ν behavior was attributed to changes in repassivation kinetics. Formerly Graduate Student at the University of British Columbia