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Fractionation of barley straw with dilute sulfuric acid for improving hemicellulose recovery
Authors:Kyung Yoen Won  Byung Hwan Um  Seung Wook Kim  Kyeong Keun Oh
Affiliation:1.Department of Applied Chemical Engineering,Dankook University,Cheonan, Chungnam,Korea;2.Department of Chemical Engineering,Hankyong National University,Anseong, Gyeonggi-do,Korea;3.Department of Chemical and Biological Engineering,Korea University,Seoul,Korea
Abstract:Dilute acid fractionation of barley straw improves dissolving hemicellulose fraction of the straw, while leaving the cellulose more reactive and accessible to enzyme as a strategy of pretreatment. To characterize the fractionation process, the effects of the acid concentration, temperature and reaction time on the hemicellulose removal as well as on the formation of by-products (furfural, 5-hydroxymethylfurfural and acetic acid) were investigated. The optimum fractionation conditions of barley straw were 1% (w/v) concentration of sulfuric acid, 158 °C of reaction temperature and 15 min of reaction time. Under the optimum conditions, 87% of xylan was hydrolyzed and recovered in liquid hydrolyzate, which was 7% higher than that of the predicted yield. The hydrolyzate contained glucose 2.44 g/L, arabinose 1.70 g/L, xylose 13.41 g/L, acetic acid 1.55 g/L, levulinic acid 0.03 g/L, 5-HMF 0.03 g/L and furfural 0.75 g/L.
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