Electrochemical performance of interfacially polymerized polyaniline nanofibres as electrode materials for non-aqueous redox supercapacitors |
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Authors: | LI Jie FANG Jing CUI Mu LU Hai ZHANG Zhi-an LAI Yan-qing |
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Affiliation: | (1) College of Chemistry, Sichuan University, Chengdu, 610064, China;(2) Analyzing and Testing Center, Sichuan University, Chengdu, 610064, China; |
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Abstract: | H+ doped polyaniline nanofibre (PH) was synthesized by interfacial polymerization and polyanilines doped with Li salt (PLI and
PHLI) were prepared by immersing emeraldine base (EB) and H+ doped polyaniline in 1 mol/L LiPF6/(EC-EMC-DMC), respectively. PH, PLI and PHLI were all characterized by scanning electron microscopy (SEM) and Fourier transform
infrared (FT-IR) spectrometry. With 1 mol/L LiPF6/(EC-EMC-DMC) as electrolyte, PH, PHLI and PLI were used as the active materials of symmetric non-aqueous redox supercapacitors.
PLI shows the highest initial specific capacitance of 120 F/g (47 F/g for PH and 66 F/g for PHLI) among three samples. After
500 cycles, the specific capacitance of PLI remains 75 F/g, indicating the good cycleability. |
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Keywords: | polyaniline nanofibre redox supercapacitor interfacial polymerization lithium salt doping |
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