Synthesis and characterization of novel polyurethanes based on fluorine‐containing polyphosphazene |
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| Authors: | Xiaobin Huang Wei Wei Jing Li Yuanli Zheng Yubo Zhou Xiaozhen Tang |
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| Affiliation: | 1. School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, People's Republic of China;2. Department of Prothodontics, Ninth People's Hospital, Shanghai Jiao Tong University School of Medicine, Shanghai Key Laboratory of Stomatology, Shanghai 200011, People's Republic of China;3. National Key Laboratory of Metallic Matrix Composite Material, Shanghai Jiao Tong University, Shanghai 200240, People's Republic of China |
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| Abstract: | Fluorine‐containing poly[bis‐(2,2,3,3,4,4,5,5‐octafluoro‐1‐pentanol)1.6 (4‐hydroxybutaneoxy)0.4 phosphazene] (OFHBP) was synthesized and characterized by Fourier transform infrared (FTIR) spectra, nuclear magnetic resonance (NMR), and gel permeation chromatography (GPC). The obtained OFHBP was used as a cross‐linker to prepare a series of novel polyurethanes (PUPFs). The composition of the PUPFs was confirmed by FTIR and elemental analysis (EA). The crystalline structure and microstructure of the PUPFs were examined by X‐ray diffraction (XRD) and atomic force microscopy (AFM). The thermal and tensile properties of the PUPFs were characterized by differential scanning calorimetry (DSC) and tensile testing. In addition, the surface energy of the PUPFs was also evaluated by contact angle measurements (CA). The results showed that glass transition temperature of the PUPF‐4 was decreased by 15°C, elongation at break was improved by 61% and a 41% decrease in surface energy in comparison with conventional polyurethane. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 |
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| Keywords: | polyurethanes polyphosphazenes fluorine‐containing glass transition surface energy |
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