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Electrospinning fabrication and characterization of poly(vinyl alcohol)/waterborne polyurethane nanofiber membranes in aqueous solution
Authors:Jeong Han Yang  Nam Sik Yoon  Jae Hyeung Park  In Kyo Kim  In Woo Cheong  Yulin Deng  Weontae Oh  Jeong Hyun Yeum
Affiliation:1. Department of Textile System Engineering, Kyungpook National University, Daegu 702‐701, Korea;2. Department of Advanced Organic Materials Science and Engineering, Kyungpook National University, Daegu 702‐701, Korea;3. Department of Applied Chemistry, Kyungpook National University, Daegu 702‐701, Korea;4. School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, Atlanta, Georgia 30332‐0620, USA;5. Department of Materials and Components Engineering, Dong‐eui University, Busan 614‐714, Korea
Abstract:Poly(vinyl alcohol) (PVA)/waterborne polyurethane (WBPU) nanofiber mats were prepared using electrospinning method with aqueous solutions. Scanning electron microscopy (SEM), X‐ray diffraction (XRD), thermal gravimetric analyzer (TGA), and tensile strength testing machine (ZWICK) were used to characterize the morphology and properties of the PVA/WBPU nanofiber mats. The results showed that the morphologies of PVA/WBPU nanofiber mats changed with the total solid concentration and the mass ratio of PVA/WBPU in the spinning solution. The tensile strength and thermal stability of the fibers could be significantly affected by the WBPU contents. The electrospun PVA/WBPU membranes showed higher water uptake, which would have potential applications in wound dressings. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011
Keywords:poly(vinyl alcohol)  waterborne polyurethane  electrospinning  nanofiber mat
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