The Mechanochemical Synthesis of NaNbO3 Using Different Ball-Impact Energies

We studied the mechanochemical synthesis of NaNbO₃ from a starting-powder mixture of sodium carbonate and Nb₂O₅ using ball-impact energies of 15 and 370 mJ/hit. Based on the results of a quantitative phase analysis we propose a mechanism for the mechanochemical synthesis of NaNbO₃. During milling a condition is established, where the amounts of perovskite, X-ray diffraction -amorphous phase and residual carbonate in the mixture do not change with increasing milling time. Similarly, the NaNbO₃ crystallite size and the quantity of microstrains reach final values that are independent of the applied ball-impact energy.