| 合成碳酸乙烯酯催化剂的研究与展望 |
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| 引用本文： | 郭立颖,吕小兵,史君,贺俊海,张彬,黄鹏程.合成碳酸乙烯酯催化剂的研究与展望[J].广州化工,2014(16):5-7,12. |
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| 作者姓名： | 郭立颖 吕小兵 史君 贺俊海 张彬 黄鹏程 |
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| 作者单位： | 大连理工大学精细化工国家重点实验室;中石油辽阳石化分公司研究院;沈阳工业大学石油化工学院 |
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| 基金项目： | 中石油辽阳石化分公司资助项目(K201303);国家级大学生创新创业训练计划项目(101422013068) |
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| 摘 要： | 简述了碳酸乙烯酯合成方法,详细介绍了环氧乙烷和二氧化碳羰基化反应制备碳酸乙烯酯催化剂的研究状况,比较了主族元素配合物催化体系、过渡金属配合物催化体系、季铵盐与季膦盐和碱金属盐催化体系、离子液体等催化体系的优势与不足,阐明了离子液体催化剂的催化机理与优势,展望了新型功能化离子液体催化体系催化羰基化反应的应用前景。
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| 关 键 词： | 碳酸乙烯酯 功能化离子液体 催化剂 羰基化反应 |
Research and Prospect of Catalyst for Synthesizing Ethylene Carbonate |
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| GUO Li-ying;LV Xiao-bing;SHI Jun;HE Jun-hai;ZHANG Bin;HUANG Peng-cheng.Research and Prospect of Catalyst for Synthesizing Ethylene Carbonate[J].GuangZhou Chemical Industry and Technology,2014(16):5-7,12. |
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| Authors: | GUO Li-ying;LV Xiao-bing;SHI Jun;HE Jun-hai;ZHANG Bin;HUANG Peng-cheng |
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| Affiliation: | GUO Li-ying;LV Xiao-bing;SHI Jun;HE Jun-hai;ZHANG Bin;HUANG Peng-cheng;Key Laboratory of Fine Chemicals,Dalian University of Technology;Research Institute,Petrochina Liaoyang Petrochemical Company;School of Petrochemical Engineering,Shenyang University of Technology; |
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| Abstract: | The synthetic methods of ethylene carbonate were described briefly.The research status of catalyst for synthesizing ethylene carbonate was explained in detail.The advantages and disadvantages of catalytic system , such as main group element complex catalyst , transition metal complexes , quaternary ammonium and phosphonium salt and alkali metal salt, ionic liquids were compared.The catalytic mechanism of ionic liquid catalyst and advantage were clarified.The development of new functional ionic liquid catalyst for carbonyl reaction was prospected in the end . |
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| Keywords: | ethylene carbonate Functional ionic liquids catalyst carbonyl reaction |
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