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PEBA/PVDF复合膜的溶胀及渗透汽化性能研究
引用本文:刘琨,祖敏辉. PEBA/PVDF复合膜的溶胀及渗透汽化性能研究[J]. 膜科学与技术, 2010, 30(1)
作者姓名:刘琨  祖敏辉
作者单位:广西大学化学化工学院,南宁,530004
基金项目:广西留学回国基金(桂科回0575002);;“广西区教育厅研究生创新基地建设”项目
摘    要:为从醋酸正丁酯稀水溶液中回收微量酯,采用涂布法制备了聚醚共聚乙酰胺/聚偏氟乙烯(PEBA/PVDF)复合膜.考察了复合膜在醋酸正丁酯稀水溶液中的溶胀性能,探讨了浸泡时间、浸泡液温度及浸泡液浓度等因素对溶胀度的影响.通过拉力试验,测试了复合膜的力学性能.通过渗透汽化实验,从醋酸正丁酯稀水溶液中分离出醋酸正丁酯,研究了料液浓度、料液温度等因素对复合膜分离性能的影响.结果显示,复合膜在醋酸正丁酯稀水溶液中具有良好的溶胀性能及渗透汽化性能;40℃下分离质量分数为0.6%的醋酸正丁酯水溶液,渗透通量达到280.43 g/(m2.h),分离因子为308.65.

关 键 词:聚醚共聚乙酰胺(PEBA)  聚偏氟乙烯(PVDF)  复合膜  溶胀  渗透汽化  

Study on swelling and pervaporation behavior of PEBA/PVDF composite membrane
LIU Kun,ZU Minhui. Study on swelling and pervaporation behavior of PEBA/PVDF composite membrane[J]. Membrane Science and Technology, 2010, 30(1)
Authors:LIU Kun  ZU Minhui
Affiliation:School of Chemistry and Chemical Engineering/a>;Guangxi University/a>;Nanning 530004/a>;China
Abstract:The aim of this work is to recycle trace N-butyl acetate from dilute aqueous solution.Polyether block amide/poly(vinylidene fluoride)(PEBA/PVDF) composite membrane was prepared by cast.The swelling behavior of membrane in N-butyl acetate dilute aqueous solution was explored.The effect of dipping time, temperature as well as concentration on the swelling degrees was also measured.Mechanical property of the membrane was investigated by stretching test.N-butyl acetate was separated from its aqueous solution by...
Keywords:polyether block amide  poly (vinylidene fluoride)  composite membrane  swelling  pervaporation
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