Towards the synthesis of electroactive block copolymers via anionic-to-Ziegler-Natta transformation reactions |
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| Authors: | Mary E. Galvin Gary E. Wnek |
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| Affiliation: | (1) Department of Materials Science and Engineering, Massachusetts Institute of Technology, 02139 Cambridge, MA, USA;(2) Present address: AT&T Bell Laboratories, 07974 Murray Hill, NJ, USA |
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| Abstract: | Summary Diblock copolymers of acetylene and styrene were prepared by treating Ti(OBu)4 with polystyryl lithium followed by reaction with acetylene. Reliable evidence for the formation of block copolymers was derived from dual radiotagging experiments. |
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