Incorporation of nitrification inhibitors with urea and urea-ammonium nitrate for irrigated corn

Nitrapyrin 2-chloro-6-(trichloromethyl)pyridine] has been shown to delay nitrification and may increase nitrogen (N) utilization efficiency of crops under N loss conditions. Current application recommendations suggest immediate incorporation. With fertilizer N sources such as urea and urea-ammonium nitrate (UAN) solution, immediate incorporation may not be practical. Experiments were conducted with irrigated corn (Zea mays L.) over 3 years to determine if nitrification inhibitor (NI) incorporation and contact with the fertilizer source was essential with urea and UAN to maintain efficacy of nitrapyrin and etridiazol 5-ethoxy-3-(trichloromethyl)-1,2,4-thiadiazole]. Nitrogen at a rate of 134 kg ha^–1 was broadcast on a Hubbard loamy coarse sand (sandy, mixed Udorthentic Haploboroll) before planting. Nitrification inhibitors were applied at 0.56 kg ha^–1 either as coating on urea, mixed with UAN, or applied in a broadcast application separate from the application of the N fertilizer. Incorporation was conducted immediately after NI application. Leaching losses, reduced N availability each year of experimentation. Nitrogen uptake from urea with no NI applied was 26% higher than uptake from UAN and resulted in 11% higher grain yields. Volatilization of urea from either N source was not apparent. Nitrapyrin and etridiazol produced similar increases in N utilization and yield. Incorporation of nitrapyrin and etridiazol was essential to obtain efficacy with both fertilizer sources. Incorporation of both NIs (averaged over NI) increased grain yields 28% with urea and 16% with UAN. Separate applications of NI provided comparable results to application with the fertilizer material if the NI was incorporated immediately.Journal Paper No. 16074 Univ. of Minnesota Agric. Expt. Sta., St. Paul, MN 55108. Contribution from the Department of Soil Science. This work was supported in part by Dow Chemical U.S.A. and the Olin Corp.