| 含异氰脲酸酯结构聚醚多元醇的合成 |
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| 引用本文： | 常海,范晓东,王生杰.含异氰脲酸酯结构聚醚多元醇的合成[J].火炸药学报,2007,30(6):13-16. |
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| 作者姓名： | 常海 范晓东 王生杰 |
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| 作者单位： | 西北工业大学理学院应用化学系,陕西,西安,710072 |
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| 摘 要： | 以1,3,5-三羟乙基异氰脲酸酯(THEIC)为引发剂、三氟化硼乙醚络合物为催化剂,环氧化合物为环单体,进行了阳离子开环聚合反应的研究.发现THEIC与环氧单体可在非均相体系中平稳地进行阳离子开环聚合反应.在THEIC体系,就链引发而言,环氧氯丙烷的大于环氧丙烷、丁基醚环氧乙烷.调整环单体加料次序就可以获得嵌段共聚醚多元醇.
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| 关 键 词： | 有机化学 聚醚多元醇 三羟乙基异氰脲酸酯 开环聚合反应 环氧单体 organic chemistry poly(ether glycol)s tris(2-hydroxythyl) isocyanurate ring opening polymerization epoxide based monomers 脲酸 酯结构 聚醚多元醇 合成 Poly Synthesis glycol ether copolymers containing block monomer feeding sequence reaction rate epichlorohydrin faster propylene oxide However ring opening |
| 文章编号： | 1007-7812(2007)06-0013-04 |
| 修稿时间： | 2007年9月7日 |
Synthesis of Poly(ether glycol)s Containing Isocyanurate Segments |
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| CHANG Hai,FAN Xiao-dong,WANG Sheng-jie.Synthesis of Poly(ether glycol)s Containing Isocyanurate Segments[J].Chinese Journal of Explosives & Propellants,2007,30(6):13-16. |
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| Authors: | CHANG Hai FAN Xiao-dong WANG Sheng-jie |
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| Abstract: | The cationic ring-opening polymerizations of epoxide based monomers were studied using tris(2-hydrooxyethyl) isocyanurate (THEIC) as initiator and trifluoroboron plus ether complex system as catalyst. It was found that the ring opening polymerizations of epoxide based monomers with THEIC can be carried out in a heterogeneous medium smoothly. However, using THEIC initiator, the reaction rate for epichlorohydrin is faster than that of propylene oxide and 2-butoxyxirane, respectively. By simply adjusting the monomer feeding sequence, the block poly(ether glycol) copolymers containing isocyanurate segments can be prepared successfully. |
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| Keywords: | organic chemistry poly(ether glycol)s tris(2-hydroxythyl) isocyanurate ring opening polymerization epoxide based monomers |
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