Ru–Ru2PΦNPC and NPC@RuO2 Synthesized via Environment‐Friendly and Solid‐Phase Phosphating Process by Saccharomycetes as N/P Sources and Carbon Template for Overall Water Splitting in Acid Electrolyte

Although numerous ruthenium‐based phosphates possess high catalytic activities for hydrogen evolution reaction (HER), most of them rely on dangerous and toxic synthesis routes. Biological slices confirm that Ru ions can penetrate the cell walls of saccharomycete, which facilitates the adsorption of Ru ions. Herein, based on a green synthesis process by saccharomycete cells as the carbon template and nitrogen/phosphorus (N/P) sources, novel Janus‐like ruthenium–ruthenium phosphide nanoparticles embedded into a N/P dual‐doped carbon matrix (Ru–Ru₂PΦNPC) electrocatalyst for HER are synthesized. Electrochemical tests reveal that Ru–Ru₂PΦNPC displays remarkable performance with a low overpotential of 42 mV at 10 mA cm^?2 and demonstrates superior stability at a high current density in 0.5 m H₂SO₄. Furthermore, ruthenium oxide nanoparticles coated N/P dual‐doped carbon (NPC@RuO₂) are also synthesized with a yolk–shell structure using saccharomycete cells as the core template and RuO₂ as a shell to isolate saccharomycete cells from the oxidation reaction during calcination in air. The NPC@RuO₂ as oxygen evolution reaction electrocatalyst possesses a low overpotential of 220 mV at 10 mA cm^?2. Finally, the Ru–Ru₂PΦNPC is integrated as a cathode and NPC@RuO₂ is integrated as an anode to construct a two‐electrode electrolyzer to enable an excellent performance for overall water splitting with a cell voltage of 1.50 V at 10 mA cm^?2 in 0.5 m H₂SO₄.