Chemical Control of Correlated Metals as Transparent Conductors

Correlated metallic transition metal oxides offer a route to thin film transparent conductors that is distinct from the degenerate doping of broadband wide gap semiconductors. In a correlated metal transparent conductor, interelectron repulsion shifts the plasma frequency out of the visible region to enhance optical transmission, while the high carrier density of a metal retains sufficient conductivity. By exploiting control of the filling, position, and width of the bands derived from the B site transition metal in ABO₃ perovskite oxide films, it is shown that pulsed laser deposition‐grown films of cubic SrMoO₃ and orthorhombic CaMoO₃ based on the second transition series cation 4d² Mo⁴⁺ have superior transparent conductor properties to those of the first transition series 3d¹ V⁴⁺‐based SrVO₃. The increased carrier concentration offered by the greater bandfilling in the molybdates gives higher conductivity while retaining sufficient correlation to keep the plasma edge below the visible region. The reduced binding energy of the n=4 frontier orbitals in the second transition series materials shifts the energies of oxide 2p to metal nd transitions into the near‐ultraviolet to enhance visible transparency. The A site size‐driven rotation of MoO₆ octahedra in CaMoO₃ optimizes the balance between plasma frequency and conductivity for transparent conductor performance.