| 芳基烷醇-β-D-葡萄糖苷的化学合成与应用 |
| |
| 引用本文： | 王灼琛,李英波,凌铁军,张雷,宛晓春,张正竹.芳基烷醇-β-D-葡萄糖苷的化学合成与应用[J].食品与发酵工业,2007,33(8):21-24. |
| |
| 作者姓名： | 王灼琛 李英波 凌铁军 张雷 宛晓春 张正竹 |
| |
| 作者单位： | 安徽农业大学茶叶生物化学与生物技术教育部、农业部重点实验室,安徽合肥,230036 |
| |
| 基金项目： | 安徽省自然科学基金;安徽省人才培养和科研带头人专项基金 |
| |
| 摘 要： | 采用改进的Helferich法立体选择合成了芳基烷醇-β-D-葡萄糖苷,合成路线比传统的Koenigs-Knorr法减少了一步,产物收率分别为53%(3a)和49%(3b),通过LC/MS、~1H-NMR、~(13)C-NMR等检测条件对产物结构进行了表征;添加芳基烷醇-β-D-葡萄糖苷对低焦油卷烟的香味具有一定的补偿作用,但转化率很低,仅为7.3%(3a)和5.03%(3b);芳基烷醇-β-D-葡萄耱苷对植物病原菌具有明显的抑制作用。
|
| 关 键 词： | 芳基烷醇-β-D-葡萄糖苷 合成 表征 增香 抑菌 |
| 修稿时间： | 2007-03-14 |
Chemical Synthesis, Identification and Application of Aryl Alcoholic-β-D-Glucosides |
| |
| Wang Zhuochen,Li Yingbo,Ling Tiejun,Zhang Lei,Wan Xiaochun,Zhang Zhengzhu.Chemical Synthesis, Identification and Application of Aryl Alcoholic-β-D-Glucosides[J].Food and Fermentation Industries,2007,33(8):21-24. |
| |
| Authors: | Wang Zhuochen Li Yingbo Ling Tiejun Zhang Lei Wan Xiaochun Zhang Zhengzhu |
| |
| Abstract: | Aryl alcoholic-β-D-glucosides were stereo-selectively synthesized through a modified Helferich route.This route was much easier and simple than the traditional Koenigs-knorr method.The total yields were 53%(3a)and 49%(3b)respectively,and the products were identified by LC/MS(liquid chromatograph/ mass spectrograph),~1H-NMR and ~(13)C-NMR.Aryl alcoholic glycosides could be used as the flavor improving materials in cigarette flavoring,while the convert rates of these compounds were very lower,7.3% for 3a and 5.03% for 3b.Benzyl-β-glucoside exhibited antifungal activities obviously. |
| |
| Keywords: | aryl aleoholic-β-D-glucosides synthesis identification flavor improving antifungal |
| 本文献已被 维普 万方数据 等数据库收录！ |
|
