| 二茂铁甲酸的合成 |
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| 引用本文： | 王世辉,洪秀云,孙蕊,金丽萍,胡春.二茂铁甲酸的合成[J].应用化工,2007,36(6):540-541. |
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| 作者姓名： | 王世辉 洪秀云 孙蕊 金丽萍 胡春 |
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| 作者单位： | 沈阳药科大学,制药工程学院,辽宁,沈阳,110016 |
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| 摘 要： | 在三氯化铝催化下,以二茂铁和邻氯苯甲酰氯反应,合成了邻氯苯甲酰二茂铁,然后用异丙醇铝裂解邻氯苯甲酰二茂铁得到二茂铁甲酸,其结构经IR和1H NMR确认。该方法用廉价的异丙醇铝代替叔丁醇钾,降低了成本。
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| 关 键 词： | 二茂铁甲酸 邻氯苯甲酰二茂铁 异丙醇铝 |
| 文章编号： | 1671-3206（2007）06-0540-02 |
| 修稿时间： | 2007-03-30 |
Synthesis of ferrocenecarboxylic acid |
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| WANG Shi-hui,HONG Xiu-yun,SUN Rui,JIN Li-ping,HU Chun.Synthesis of ferrocenecarboxylic acid[J].Applied chemical industry,2007,36(6):540-541. |
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| Authors: | WANG Shi-hui HONG Xiu-yun SUN Rui JIN Li-ping HU Chun |
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| Affiliation: | School of Pharmaceutical Engineering, Shenyang Pharmaceutical University, Shenyang 110016, China |
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| Abstract: | Ferrocenecarboxylic acid,2-chlorobenzoylferrocene was synthesized by the reaction of ferrocene and 2-chlorobenzoylchloride,aluminum trichloride as the catalyst,then ferrocenecarboxylic acid was prepared by the reaction of 2-chlorobenzoylferrocene and aluminum isopropoxide.Its structure was characterized by IR and 1H NMR.The replacement of potassium tert-butoxide with aluminum isopropoxide result in cost reduction in preparation of ferrocenecarboxylic acid. |
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| Keywords: | ferrocenecarboxylic acid 2-chlorobenzoylferrocene aluminum isopropoxide |
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