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微波场中冶金固体废弃物脱硫脱硝的非热效应分析
引用本文:刘金鑫,;金永龙,;韩庆虹,;苍大强.微波场中冶金固体废弃物脱硫脱硝的非热效应分析[J].武汉冶金科技大学学报,2009(2):131-133.
作者姓名:刘金鑫  ;金永龙  ;韩庆虹  ;苍大强
作者单位:[1]辽宁科技大学材料科学与工程学院,辽宁鞍山114051; [2]北京科技大学冶金与生态工程学院,北京100083
基金项目:辽宁省科技基金资助项目(20041085).
摘    要:从微波的非热效应对微波改性吸收剂的吸附机理进行了分析,应用莫尔斯振子模型和拉曼谱峰图,讨论吸收剂在微波改性前后莫尔斯势能的变化情况。结果显示,微波改性后吸附剂的莫尔斯势能从原样的118.59kJ/mol降至70kJ/mol以下。

关 键 词:微波  非热效应  莫尔斯振子  模型

Non-thermal effect of desulfurization and denitration of solid metallurgical waste in the field of microwave
Affiliation:Liu Jinxin , Jin Yonglong ,Han Qinghong , Cang Daqiang (1. School of Materials Science and Engineering, University of Science and Technology Liaoning, Anshan 114051, China; 2. School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China)
Abstract:The adsorption mechanism of the absorbent modified by microwave is discussed from the non-thermal effect of microwave. The Morse oscillator model and Raman spectra are applied to the discussion of the change in Morse potential energy of the absorbent before and after microwave modificatiofi. The results show that the Morse potential energy of the absorbent modified by microwave has decreased from 118.59 kJ/mol (original sample) to 70 kJ/mol.
Keywords:microwave  non-thermal effect  Morse oscillator  model
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