| 氟化物催化剂合成1,1 1,2 一四氟乙烷的进展 |
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| 引用本文： | 吕剑,李惠黎.氟化物催化剂合成1,1 1,2 一四氟乙烷的进展[J].工业催化,1996,4(2):11-16. |
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| 作者姓名： | 吕剑 李惠黎 |
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| 作者单位： | (西安近代化学研究所 西安 710061) |
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| 摘 要： | 综述了以三抓乙烯为原料经1,1 ,1-三氟-2-氮乙烷(HCFC-133a)中间体, 气相催化氮化合成1,1 ,1 ,2-四氟乙烷(HFC-134a)的催化剂及其载体, 反应条件选择等的研究进展, 探讨了卤素交换反应机理。建议开发具有高氟化性能、AlF3负载的低铬或非铬催化剂。
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| 关 键 词： | 催化剂氟化 氟化 1，1，1，2-四氟乙烷 |
Advances in Synthesis of1,1,1,2-tetrafluoroethane (HFC-134a) over Fluoride Catalysts |
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| Lv Jian,Li Huili,Peng Shaoyi.Advances in Synthesis of1,1,1,2-tetrafluoroethane (HFC-134a) over Fluoride Catalysts[J].Industrial Catalysis,1996,4(2):11-16. |
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| Authors: | Lv Jian Li Huili Peng Shaoyi |
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| Affiliation: | (Xi'an Modern chemistry Res Inst,Xi'an,710600) |
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| Abstract: | Researches on the catalysts,carriers and reaction conditions for the synthesis of HFC-134a from trichoroethylene by gasous phase catalytic fluorination,via HCFC-133a intermediate,were reviewed. The mechanisms of halogen exchange reaction were also outline.It is suggested that AlF3 supported metal catalysts with higher fluorinating performance and less Gr3+ or other metal be developed. |
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| Keywords: | fluorination 1 1 1 2-tetrafluoroethane aluminum trifloride catalust |
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