| 9-蒽甲胺的合成 |
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| 引用本文： | 王奇观,曹永军,王素敏. 9-蒽甲胺的合成[J]. 精细化工中间体, 2010, 40(2): 61-63 |
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| 作者姓名： | 王奇观 曹永军 王素敏 |
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| 作者单位： | 1. 西安工业大学,材料与化工学院,陕西,西安,710032
2. 驻马店教育学院,河南,驻马店,463000 |
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| 摘 要： | 以9-蒽甲醇为原料,通过溴化、叠氮基亲核取代、催化氢化3步反应制备了9-蒽甲胺,总收率达60%。利用1HNMR、质谱、元素分析对产物的组成和结构进行了确认和鉴定。研究结果表明,以Pd/C为催化剂,催化氢化在常温常压下能够快速进行,40min就可完全反应。
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| 关 键 词： | 9-蒽甲胺 9-蒽甲醇 合成 |
The Synthesis of 9-Aminomethylanthracene |
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| WANG Qi-guan,CAO Yong-jun,WANG Su-min. The Synthesis of 9-Aminomethylanthracene[J]. Fine Chemical Intermediates, 2010, 40(2): 61-63 |
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| Authors: | WANG Qi-guan CAO Yong-jun WANG Su-min |
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| Affiliation: | 1. School of Material and Chemical Engineering, Xi＇an Technological University, Xi＇an 710032, China; 2. Zhumadian Institute of Education, Zhumadian 463000, China) |
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| Abstract: | 9-Aminomethylanthracene is a versatile intermediate in organic synthesis. In this paper it was prepared from 9-anthylmethanol in three steps, including bromination, nucleophilic replacement with azid and Pd/C catalyzed hydrogenation, in 60% overall yield. The hydrogenation finished within 40 min at room temperature and under atmospheric pressure. The structure of the target compound was characterized with ^1H NMR, ESI-MS and elemental analysis. |
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| Keywords: | 9-aminomethylanthracene 9-anthylmethanol systhesis |
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