| 可聚合高分子乳化剂的合成及溶液性质研究 |
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| 引用本文： | 方治齐,陈宏伟,刘春华,张新云,董其宝,李志明. 可聚合高分子乳化剂的合成及溶液性质研究[J]. 高分子材料科学与工程, 2002, 18(6): 196-198 |
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| 作者姓名： | 方治齐 陈宏伟 刘春华 张新云 董其宝 李志明 |
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| 作者单位： | 合肥工业大学化工学院,安徽,合肥,230009 |
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| 摘 要： | 研究了作为乳化剂的可聚合两亲嵌段聚合物的嵌段组成，特别是端基结构与其水溶液的浊点、粘度、临界胶束浓度以及表面张力之间的关系。发现可聚合高分子乳化剂的结构和分子量存在多分散性，溶液中的胶束形态也存在多分散性。监测两亲聚合物水溶液的上述性质可有效地指导两亲嵌段嵌合物的合成。
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| 关 键 词： | 可聚合高分子乳化剂 合成 溶液性质 研究 两亲聚合物 浊点 |
| 文章编号： | 1000-7555(2002)06-0196-03 |
| 修稿时间： | 2001-07-28 |
STUDY ON SYNTHESIS OF POLYMERISABLE MACROMOLECULE EMULSIFIER AND SOLUTION PROPERTIES |
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| FANG Zhi-qi,CHEN Hong-wei,LIU Chun-hua,ZHANG Xin-yun,DONG Qi-bao,LI Zhi-ming. STUDY ON SYNTHESIS OF POLYMERISABLE MACROMOLECULE EMULSIFIER AND SOLUTION PROPERTIES[J]. Polymer Materials Science & Engineering, 2002, 18(6): 196-198 |
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| Authors: | FANG Zhi-qi CHEN Hong-wei LIU Chun-hua ZHANG Xin-yun DONG Qi-bao LI Zhi-ming |
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| Abstract: | The connection of the block composition of polymerisable amphiphilic block polymer HTP used as emulsifier especially the end group structure and the special properties including cloud point, viscosity, CMC, and the surface tension of the aqueous solution has been investigated. It is found that multi-dispersity exists in the structure and the molecular weight of the polymerisable macromolecule emuisifier and the micelle configuration has the same property.It is effective to instruct the synthesis of the amphiphilic block polymer by testing the property in aqueous solution. |
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| Keywords: | emulsifier amphiphilic polymer solution property cloud point |
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