| 有机硅氧烷-丙烯酸酯乳液聚合研究 |
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| 引用本文： | 张晓镭,顾玲杰. 有机硅氧烷-丙烯酸酯乳液聚合研究[J]. 中国皮革, 2005, 34(11): 29-30 |
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| 作者姓名： | 张晓镭 顾玲杰 |
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| 作者单位： | 陕西科技大学资源与环境学院,咸阳712081 |
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| 基金项目： | 本论文受到陕西省自然科学研究项目资助(项目编号:2003B08) |
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| 摘 要： | 采用单体后滴加法,用八甲基环四硅氧烷(D4)和γ-甲基丙烯酰氧基丙基三甲氧基硅烷(A-174),对丙烯酸酯乳液进行改性,通过乳液聚合合成有机硅-丙烯酸酯共聚物.对其合成工艺进行了初步探索,通过红外光谱、DSC分析,对产物进行了表征,考察了不同有机硅含量对共聚产物的成膜性能、胶膜拉伸强度、胶膜伸长率的影响.
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| 关 键 词： | 八甲基环四硅氧烷 γ-甲基丙烯酰氧基丙基三甲氧基硅烷 丙烯酸酯 乳液聚合 |
Study of organosiloxane-acrylate emulsion polymerization |
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| Zhang Xiaolei,Gu Lingjie. Study of organosiloxane-acrylate emulsion polymerization[J]. China Leather, 2005, 34(11): 29-30 |
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| Authors: | Zhang Xiaolei Gu Lingjie |
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| Abstract: | The procedure for preparing the acrylate on copolymers modified with D4 and A-174 as their Ts were characterized by IR and DSC. The tensile and peeling strength and hydroscopicity of polymer films were also studied and analysized in accordance with the copolymer's structures,prepared by emulsion polymerization possess excellent mechanical property and climatic resistance. |
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| Keywords: | octamethylcycloterasiloxane 3-(trimethoxysily) propylmethacrylate acrylate emulsion polymerization |
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