Activity-composition relations at 1100°C in the system calcium oxide-iron oxide-manganese oxide in contact with metallic iron |
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Authors: | Nils Tiberg Arnulf Muan |
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Affiliation: | 1. Oxel?sunds J?rnverk, Sweden 2. Department of Geochemistry and Mineralogy, The Pennsylvania State University, Pennsylvania, USA
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Abstract: | The extent of the solid miscibility gap in the system CaO−“FeO”−MnO at 1100°C has been determined termined by electron microprobe, point-counting, and X-ray diffraction analysis of coexisting phases within the miscibility gap. Activities of FeO in ternary solid solutions have been determined at 1100°C by equilibrating the solid solutions with metallic iron and a gas phase of known oxygen pressures. Activity-composition curves for CaO and MnO in the ternary system are calculated from a Gibbs-Duhem integration, and the data are extrapolated to the binary system CaO−MnO, which is shown to display a considerable positive deviation from ideality at 1100°C. NILS TIBERG, formerly Graduate Assistant, Department of metallurgy, The Pennsylvania State Univeristy, University Park, Pa. |
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