| 4,5-二芳基噁唑的光化学环化消除合成菲并[9,10-d]噁唑 |
| |
| 引用本文： | 石晓东. 4,5-二芳基噁唑的光化学环化消除合成菲并[9,10-d]噁唑[J]. 感光科学与光化学, 1990, 0(3) |
| |
| 作者姓名： | 石晓东 |
| |
| 作者单位： | 机械电子工业部上海电缆研究所 上海 |
| |
| 摘 要： | 具有异芪生色团结构的分子是有机光化学研究的重要对象。4,5-二芳基嗯唑(1)具有部分结构与异芪类似,本文对其分子内环化消除过程和产物进行了研究。 本文认为1的环化消除过程如下:
|
| 关 键 词： | 噁唑 光化学环化消除 Woodward-Hoffmann规则 自由价理论 |
SYNTHESIS OF PHENANTHRO [9, 10-d] OXAZOLES BY PHOTO-CYCLOELIMINATION OF 4,5-DIAROMATIC SUBSTITUTED OXAZOLES |
| |
| SHI XIAO-DONG. SYNTHESIS OF PHENANTHRO [9, 10-d] OXAZOLES BY PHOTO-CYCLOELIMINATION OF 4,5-DIAROMATIC SUBSTITUTED OXAZOLES[J]. Photographic Science and Photochemistry, 1990, 0(3) |
| |
| Authors: | SHI XIAO-DONG |
| |
| Abstract: | The photo-cycloelimination of 4,5-diaromatic substituted oxazoles was investigated.The reaction mechanism was discussed with the Woodward-Hoffmann rule and free valence theory,respectively Three phenanthro (9,10-d) oxazoles were synthesized and characterized. |
| |
| Keywords: | oxazole photo-cyclielominarion Woodward-Hoffmann rule free valence theory |
| 本文献已被 CNKI 等数据库收录！ |
|
