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PVC用UV固化聚氨酯丙烯酸酯胶粘剂的研究
引用本文:袁清峰,高延敏,浦建光,周宏建. PVC用UV固化聚氨酯丙烯酸酯胶粘剂的研究[J]. 粘接, 2009, 0(3): 51-53
作者姓名:袁清峰  高延敏  浦建光  周宏建
作者单位:江苏科技大学材科科学与工程学院,江苏,镇江,212003
摘    要:采用聚氨酯丙烯酸酯预聚体,添加光引发剂、活性稀释剂、增塑剂及偶联剂等制成PVC用UV固化胶粘剂。结果表明,当活性稀释剂质量分数为20%-25%,且mHDDA:mTGPDA:mPO3TMPTA=2:2:1、硅烷偶联剂质量分数为3%-5%、光引发剂用量为3%~5%,且m1173:m184=1.0:1.5时,用自制表面处理剂对PVC进行处理,胶粘剂粘接的剪切强度为15MPa.综合性能较好。适合于软质PVC的粘接。

关 键 词:聚氨酯丙烯酸酯  光固化  活性稀释剂  表面处理

Research of UV-curable polyurethane acrylic adhesive for PVC
YUAN Qing-feng,GAO Yan-min,PU Jian-guang,ZHOU Hong-jian. Research of UV-curable polyurethane acrylic adhesive for PVC[J]. Adhesion in China, 2009, 0(3): 51-53
Authors:YUAN Qing-feng  GAO Yan-min  PU Jian-guang  ZHOU Hong-jian
Affiliation:(School of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang,Jiangsu 212003, China)
Abstract:In this paper, the UV-curable adhesive for PVC was prepared using PUA prepolymer, photoinitiators,active diluent,plasticizer and coupling agent.The experiment results showed that when the content of active diluent,coupling agent and photoinitiators was 20-25%,3-5% and 3-5% by weight.respectively,mHDDA:mTGPDA:mPO3TMPTA=2:2:1,m1173:m184=1.0 : 1.5 and PVC treated with the self-prepared surface treating agent,the shearing strength of adhesive is 15 MPa,the adhesive has good combination property,and can be used for soft - PVC.
Keywords:PUA  UV-curahle  active diluent  surface treatment
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