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含二长链烷基溴化铵的合成及其缓蚀性能和吸附模型的研究
引用本文:夏明珠,严莲荷.含二长链烷基溴化铵的合成及其缓蚀性能和吸附模型的研究[J].腐蚀与防护,1999,20(7):324-326,299.
作者姓名:夏明珠  严莲荷
作者单位:南京理工大学化院水处理研究所 南京210094 (夏明珠,严莲荷,雷武),南京理工大学化院水处理研究所 南京210094(陈民生)
摘    要:以二甲基十六烷基胺等为原料,合成了十六烷基辛基二甲基溴化铵和十六烷基癸基二甲基溴化铵,用线性极化法研究了它们对5%HCl中碳钢的缓蚀作用,并确定了它们的吸附模型。结果表明:它们对酸液中碳钢的腐蚀具有明显的抑制作用,在碳钢表面的吸附遵循Langmuir等温式。

关 键 词:季铵盐  缓蚀  吸附  腐蚀  模型  缓蚀剂  烷基溴化铵

SYNTHESIS INHIBITION PROPERTIES AND ADSORPTION MODEL OF AMMONIUM BROMIDE WITH TWO LONG CHAIN ALKYLS
Xia Mingzhu Yan Lianhe Lei Wu Cheng Mingshen.SYNTHESIS INHIBITION PROPERTIES AND ADSORPTION MODEL OF AMMONIUM BROMIDE WITH TWO LONG CHAIN ALKYLS[J].Corrosion & Protection,1999,20(7):324-326,299.
Authors:Xia Mingzhu Yan Lianhe Lei Wu Cheng Mingshen
Abstract:Hexadecyl octyl dimethyl ammonium bromide and hexadecyl decyl dimethyl ammonium bromide were synthesized from N,N-dimethyl hexadecyl amine, their corrosion inhibition on mild steel in 5% hydrochloric acid were studied by linear polarization and their adsorption model was determined. It was found that they have obvious inhibition on mild steel in acidic media, their adsorption on the surface of mild steel obeyed the langmuir adsorption isotherm.
Keywords:Quaternary ammonium salt Corrosion inhibition Adsorption Corrosion
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