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Photocatalytic hydrogen evolution from aqueous solutions of organophosphorous compounds
Authors:Ekaterina A. Kozlova  Alexander V. Vorontsov
Affiliation:Boreskov Institute of Catalysis and Novosibirsk State University, Novosibirsk 630090, Russian Federation
Abstract:Photocatalytic hydrogen production from water solutions of dimethyl methylphosphonate (DMMP), trimethyl phosphate (TMP), triethyl phosphate (TEP), and radiation protective amine WR 2721, that imitate nerve chemical warfare agents was studied for the first time. Platinized titianium dioxide Degussa P25 was used as catalyst. No significant hydrogen evolution was detected without organic electron donors – sacrificial agents.
Keywords:Photocatalysis   Hydrogen production   Nerve gases simulants destruction   Organophosphorous compounds
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