Femtosecond laser fabrication and characterization of microchannels and waveguides in methacrylate-based polymers |
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Authors: | Carmela De Marco Raffaella Suriano Marinella Levi Stefano Turri Shane Eaton Giulio Cerullo Roberto Osellame |
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Affiliation: | (1) Dipartimento di Chimica, Materiali e Ingegneria Chimica “Giulio Natta”, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milan, Italy;(2) Istituto di Fotonica e Nanotecnologie (IFN)-CNR e Dipartimento di Fisica, Politecnico di Milano, Piazza Leonardo da Vinci 32, 20133 Milan, Italy |
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Abstract: | Femtosecond laser ablation is a promising method for producing polymeric microfluidic devices: it is a high precision processing
technology resulting from an efficient energy deposition, while simultaneously minimizing heat conduction and thermal damage
to the surrounding material. This work reports on the characterization of microchannels and waveguides fabricated by femtosecond
laser technology in methacrylate-based polymers, precisely in thermoplastic poly(methyl methacrylate) (PMMA) and in a new
material based on a high efficiency UV-curing process of methacrylic monomers bearing hydrophilic polyethylene glycol chains,
namely tetraethylene glycol dimethacrylate and poly(ethylene glycol) methacrylate (PEG-MA). Microchannels in PMMA and PEG-MA,
fabricated by parallel multi-scans, have sharp edges and low roughness, as investigated by Environmental Scanning Electron
Microscopy and laser profilometer. Surface and physico-chemical properties after fs-laser processing were further studied
by contact angle measurements and Attenuated Total Reflectance FTIR spectroscopy. Moreover, preliminary tests showed the refractive
index of fs-laser PEG-MA exposed zones is different with respect to that of the surrounding polymer, suggesting that PEG-MA
can be a good candidate to manufacture microfluidic devices containing integrated optic elements. |
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