Modeling of the non-catalytic semi-batch esterification of palm fatty acid distillate (PFAD) |
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Authors: | Seok Won Hong Hyun Jun Cho Soo Hyun Kim Yeong Koo Yeo |
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Affiliation: | (1) Novozymes, Krogshoejvej 36, 2880 Bagsvaerd, Denmark;(2) Desmet-Ballestra, Minervastraat 1, 1930 Zaventem, Belgium |
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Abstract: | Biodiesel fuel is one of the most attractive alternatives to the traditional diesel fuel derived from a petroleum refinery.
Development of a reliable model for the biodiesel production process requires maximizing economics and enhancing safety in
the commercial operation of biodiesel plants. We propose a model which represents effectively the non-catalytic biodiesel
production reaction. In the modeling of the reaction, we employ a nonlinear programming scheme to estimate reaction kinetic
parameters which minimize a specified objective function. The behavior of the methanol during the reaction is investigated
both experimentally and numerically. Imperfect mixing in the liquid phase at the initial reaction stage causes a little discrepancy
between the experimental data and results of simulations. Overall, the proposed model represents the biodiesel production
reaction effectively. |
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