| 金属酞菁接枝纤维素纤维及其消臭性能 |
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| 引用本文： | 汪进前,魏莉莉,吕素芳,张利,陈文兴.金属酞菁接枝纤维素纤维及其消臭性能[J].纺织学报,2006,27(6):5-7. |
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| 作者姓名： | 汪进前 魏莉莉 吕素芳 张利 陈文兴 |
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| 作者单位： | 浙江理工大学,先进纺织材料与制备技术教育部重点实验室,浙江,杭州,310018 |
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| 基金项目： | 中国科学院资助项目;教育部新世纪优秀人才支持计划;浙江省重点国际合作项目 |
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| 摘 要： | 采用顺丁烯二酸酐改性四氨基钴酞菁制备新型水溶性钴酞菁,并对其进行了元素分析和红外光谱表征。将金属酞菁接枝到纤维素纤维上制备功能纤维。在室温条件下,该功能纤维能有效去除甲硫醇和氨气,甲硫醇按催化氧化机理去除,而氨气按酸碱中和机理去除,2 h的去除率分别为69.7%和97.6%。
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| 关 键 词： | 四氨基钴酞菁 顺丁烯二酸酐 纤维素纤维 消臭 |
| 文章编号： | 0253-9721（2006）06-0005-03 |
| 收稿时间： | 2005-08-19 |
| 修稿时间： | 2005-11-29 |
Grafting metal phthalocyanine onto the cellulose fiber and its deodorizing effect |
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| WANG Jin-qian,WEI Li-li,L Su-fang,ZHANG Li,CHEN Wen-xing.Grafting metal phthalocyanine onto the cellulose fiber and its deodorizing effect[J].Journal of Textile Research,2006,27(6):5-7. |
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| Authors: | WANG Jin-qian WEI Li-li L Su-fang ZHANG Li CHEN Wen-xing |
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| Affiliation: | WANG Jin-qian,WEI Li-li,L(U) Su-fang,ZHANG Li,CHEN Wen-xing |
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| Abstract: | A) novel aqueous cobalt phthalocyanine was prepared by modification of cobalt tetraaminophthalocyanine with maleic anhydride and characterized by element analysis and FT-IR.Functional cellulose fibers were obtained by grafting metal phthalocyaniel(MPc) onto cellulose fibers,which can effectively remove methanthiol and ammonia at room temperature.The former was removed by the mechanism of catalytic oxidation, and the latter by the mechanism of neutralization.And the removal ratios after(2 h) were 69.7% and 97.6% respectively. |
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| Keywords: | cobalt tetraaminophthalocyanine maleic anhydride cellulose fiber deodorizing |
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