Electron microscopy of Ag–(Ni–O) core–shell nanowires

This report provides information about an electrodeposition‐based two‐step synthesis methodology for producing core–shell Ag–(Ni–O) nanowires and their detailed structural and compositional characterization using electron microscopy technique. Nanowires were produced by employing anodic alumina templates with a pore diameter of 200 nm. In the first step of the synthesis process, nanocrystalline Ni–O was electrodeposited in a controlled manner such that it heterogeneously nucleated and grew only on the template pore walls without filling the pores from bottom upwards. This alumina template with pore walls coated with Ni–O was then utilized as a template during the electrodeposition of Ag in the second step. Electrodeposited Ag filled the template pores to finally produce Ag–(Ni–O) core–shell nanowires with an overall diameter of 200 nm.