Poly(vinyl chloroformate) and derivatives: 2. Copolymerization of vinyl chloroformate and of phenyl vinyl carbonate with vinyl monomers |
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| Authors: | Gilles Meunier Patrick Hémery Sylvie Boileau |
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| Affiliation: | Laboratoire de Chimie Macromoléculaire associé au CNRS, Collège de France, 11 place Marcelin Berthelot, 75231 Paris Cedex 05, France |
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| Abstract: | Vinyl chloroformate and phenyl vinyl carbonate have been copolymerized with vinyl acetate in methylene chloride at 35°C, using dicyclohexylperoxydicarbonate as initiator. The copolymerization parameters obtained show that vinyl chloroformate and vinyl acetate have nearly the same reactivity whereas phenyl vinyl carbonate is slightly less reactive than vinyl acetate. |
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| Keywords: | Vinyl chloroformate phenyl vinyl carbonate vinyl acetate copolymerization reactivity ratios characterization |
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