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1,1–二氨基–2,2–二硝基乙烯的合成研究进展
引用本文:冯晓晶,马会强,张寿忠,苗成才,马英华. 1,1–二氨基–2,2–二硝基乙烯的合成研究进展[J]. 化学推进剂与高分子材料, 2012, 0(2): 24-29
作者姓名:冯晓晶  马会强  张寿忠  苗成才  马英华
作者单位:黎明化工研究院
摘    要:1,1–二氨基–2,2–二硝基乙烯(FOX–7)作为含能材料中典型的炸药,因具有高能钝感的特性,其合成方法受到广泛的关注。主要介绍了国内外近年来合成FOX–7的3条反应路线及改进方法,通过对各种合成方法的比较,认为采用2–甲基–4,6–二羟基嘧啶为原料改进的2–甲基–4,6–嘧啶二酮法具有应用潜力,并对FOX–7的应用前景进行了展望。

关 键 词:1,1–二氨基–2,2–二硝基乙烯  FOX–7  钝感炸药  合成方法  研究进展

Research Progress in Synthesis of 1,1-Diamino-2,2-Dinitroethylene
FENG Xiaojing,MA Huiqiang,ZHANG Shouzhong,MIAO Chengcai,MA Yinghua. Research Progress in Synthesis of 1,1-Diamino-2,2-Dinitroethylene[J]. Chemical Propellants & Polymeric Materials, 2012, 0(2): 24-29
Authors:FENG Xiaojing  MA Huiqiang  ZHANG Shouzhong  MIAO Chengcai  MA Yinghua
Affiliation:(Liming Research Institute of Chemical Industry,Luoyang 471000,China)
Abstract:As a typical explosive in energetic materials,there is a wide focus on the synthesis methods of 1,1-diamino-2,2-dinitroethylene(FOX-7) due to its high energy and low sensitivity.Three reaction routes and improved methods for preparing FOX-7 at home and abroad in recent years are mainly introduced.Compared with various synthesis methods,it is considered that the improved 2-methyl-4,6-pyrimidinedione method using 2-methyl-4,6-dihydroxy pyrimidine as raw material has application potential.The application prospect of FOX-7 is predicted.
Keywords:1,1-diamino-2,2-dinitroethylene  FOX-7  insensitive explosive  synthesis method  research progress
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