Controllable synthesis of polyoxymethylene dimethyl ethers by ionic liquids encapsulated in mesoporous SBA-16 |
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Authors: | Chaofeng Zhang Tonglu Zhang Jing Zhang Jiandong Zhang Ruifeng Li |
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Affiliation: | 1.College of Biomedical Engineering, Taiyuan University of Technology, Taiyuan 030024, China;2.College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China |
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Abstract: | The promising combustion and emission properties of polyoxymethylene dimethyl ethers (PODEn) are of significant interest. However, the synthesis of PODEn products with desired chain lengths is still a prob-lem facing synthetic PODEn. Herein, a series of unique IL@SBA-16-Cx solid catalysts are prepared by encapsulation of ionic liquids (ILs) within the nanocage of SBA-16 through a silylation method. The struc-ture of the encapsulated catalyst was characterized by UV–vis spectra, Fourier transform infrared (FT-IR), N2 adsorption–desorption isotherms, Powder X-ray diffraction (XRD), Transmission electron microscopy (TEM) and Elemental analysis. The encapsulated catalysts show similar catalytic activity to the homoge-neous counterparts and display higher selectivity to the targeted PODE3–5 products than their homoge-neous counterparts in the synthesis of PODEn from methanol (MeOH) and trioxymethylene (TOM). The encapsulated catalysts exhibit a superior PODE3–5 selectivity and could be the promising catalysts for PODEn synthetic reaction. |
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Keywords: | SBA-16 Polyoxymethylene dimethyl ethers Ionic liquids Heterogeneous catalyst Diesel fuel additives |
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