One-step conversion of syngas to light olefins over bifunctional metal-zeolite catalyst |
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Authors: | Ce Du Linet Gapu Chizema Emmerson Hondo Mingliang Tong Qingxiang Ma Xinhua Gao Ruiqin Yang Peng Lu Noritatsu Tsubaki |
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Affiliation: | 1.Zhejiang Provincial Key Lab for Chem. & Bio. Processing Technology of Farm Product, School of Biological and Chemical Engineering, Zhejiang University of Science and Technology, Hangzhou 310023, China;2.Department of Applied Chemistry, School of Engineering, University of Toyama, Gofuku 3190, Toyama 930-8555, Japan;3.State Key Laboratory Cultivation Base of Natural Gas Conversion, Ningxia University, Yinchuan 750021, China |
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Abstract: | Light olefins (C2-C4) are fundamental building blocks for the manufacture of polymers,chemical intermediates,and solvents.In this work,we realized a composite catalyst,comprising MnxZry oxides and SAPO-34 zeolite,which can convert syngas (CO + H2) into light olefins.MnxZry oxide catalysts with different Mn/Zr molar ratios were facilely prepared using the coprecipitation method prior to physical mixing with SAPO-34 zeolite.The redox properties,surface morphology,electronic state,crystal structure,and chemical elemental composition of the catalysts were examined using H2-TPR,SEM,XPS,XRD,and EDS techniques,respectively.Tandem reactions involved activation of CO and subsequent hydrogenation over the metal oxide catalyst,producing methanol and dimethyl ether as the main reaction intermediates,which then migrated onto SAPO-34 zeolite for light olefins synthesis.Effects of temperature,pressure and reactant gas flow rate on CO conversion and light olefins selectiv-ity were investigated in detail.The Mn1Zr2/SAPO-34 catalyst (Mn/Zr ratio of 1∶2) attained a CO conversion of 10.8% and light olefins selectivity of 60.7%,at an optimized temperature,pressure and GHSV of 380 ℃,3 MPa and 3000 h-1 respectively.These findings open avenues to exploit other metal oxides with CO activation capa-bilities for a more efficient syngas conversion and product selectivity. |
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Keywords: | Catalyst C-C coupling CO activation Hydrogenation Light olefins Syngas |
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