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钢管支架内壁磷化膜生锈失效原因分析
引用本文:宋泓清,隋永强,周娟,高海平. 钢管支架内壁磷化膜生锈失效原因分析[J]. 现代涂料与涂装, 2013, 0(12): 43-44
作者姓名:宋泓清  隋永强  周娟  高海平
作者单位:中国船舶重工集团公司第七二五研究所海洋腐蚀与防护国防科技重点实验室,山东青岛266101
摘    要:通过对磷化膜微观形貌、元素组成以及对磷化液pH值及化学成分的分析,结果表明磷化过程中磷化液酸度过高,造成磷化晶粒过细,成膜不均匀,膜层厚度较薄,是导致钢管支架内壁磷化膜在较短时间内生锈失效的主要原因。通过调整控制镀液pH值1.5~2.0,新制备的磷化膜厚度及均匀性大大增加,其耐蚀性能得到有效提高。

关 键 词:磷化  耐蚀性  能谱分析

Analysis of Invalidation Causes of Phosphating Film Rust on the Inner Wall of Steel Pipe Scaffold
SONG Hong-qing,SUI Yong-qiang,ZHOU Juan,GAO Hai-ping. Analysis of Invalidation Causes of Phosphating Film Rust on the Inner Wall of Steel Pipe Scaffold[J]. Modern Paint and Finishing, 2013, 0(12): 43-44
Authors:SONG Hong-qing  SUI Yong-qiang  ZHOU Juan  GAO Hai-ping
Affiliation:Ship Malerial Research Institute, National Laboratory" for Marine Corrosion and Protection, Qingdao Shangdong 266101, China)
Abstract:Through analysis of morphology, composition of phosphating film,pH value and composition of phosphating solution, the results showed that the excessive acidity inducing excessively fine crystals, discontinuous and thin film resulted in corrosion of phosphating film. After controlling 1.5-2.0 of pH in solution, characteristics of new phosphating fihn was effectively improved.
Keywords:phosphating  corrosion resistanee  EDX analysis
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