The electrocatalytic hydrogenation of soybean oil |
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Authors: | G J Yusem P N Pintauro |
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Affiliation: | (1) Department of Chemical Engineering, Tulane University, 70118 New Orleans, Louisiana |
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Abstract: | Soybean oil has been hydrogenated electrocatalytically at a moderate temperature, without an external supply of pressurized
H2 gas. In the electrocatalytic reaction scheme, atomic hydrogen is produced on an active Raney nickel powder cathode surface
by the electrochemical reduction of water molecules from the electrolytic solution. Adsorbed hydrogen then reacts with an
oil’s triglycerides to form a hydrogenated product. Experiments were carried out at 70°C with a flow-through electrochemical
reactor operating in a batch recycle mode. The reaction medium was a two-phase mixture of soybean oil in a water/t-butanol
solvent containing tetraethylammoniump-toluenesulfonate as the supporting electrolyte. In all experiments the reaction was allowed to continue for sufficient time
to synthesize a brush hydrogenation product. The effects of oil content, applied current, solvent composition, and supporting
electrolyte concentration on the efficiency of hydrogen addition to the oil and on the chemical properties of the hydrogenated
oil product were determined. The electrohydrogenated oil is characterized by a high stearic acid content and a low percentage
of totaltrans isomers, as compared to that produced in a traditional hydrogenation process. |
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Keywords: | Current current efficiency electrochemical electrolyte hydrogenated Raney nickel soybean oil |
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