Temperature dependence of the local Seebeck coefficient near the boundary in touching Cu/Bi–Te/Cu composites

The thermo-emf ΔV and temperature difference ΔT across the boundary were measured as functions of r and I for the touching p- and n-type Cu/Bi–Te/Cu composites composed of t _Bi–Te = 2.0 mm and t _Cu = 0.3 mm, where r is the distance from the boundary and I is a direct current producing ΔT which flows through two Peltier modules connected in series. The resultant Seebeck coefficient α across the boundary is obtained from the relation α = ΔV/ΔT. As a result, the resultant |α| of the touching p- and n-type composites have a great local maximum value at r ≈ 0.03 mm and decrease rapidly with further increase of r to approach the intrinsic |α_Bi–Te|. The maximum resultant α of the p- and n-type composites reached great values of 1,043 and −1,187 μV/K at 303 K corresponding to I = 0.8 A and of 1,477 and −725 μV/K at 360 K corresponding to I = 2.0 A. Reflecting the temperature dependence of the intrinsic α_Bi–Te, the maximum α of the p-type composite increases with an increase of T, while that of the n-type one decrease with an increase of T. Surprisingly, the maximum α of the p- and n-type composites have great gradients of 8.36 and −7.15 μV/K² in the range from 303 to 366 K, respectively, which are 21.8 and 134 times larger in absolute value than 0.383 and −0.0535 μV/K² of the intrinsic p- and n-type α_Bi–Te, so that the maximum resultant α was thus found to be much more sensitive to temperature than the intrinsic α_Bi–Te. Moreover, the local Seebeck coefficient α _l (r) derived analytically from the resultant α(r) is enhanced significantly in the narrow region below r ≈ 0.05 mm and the maximum α _l values of the p- and n-type composites were found to have extremely great values of approximately 1,800 μV/K at 360 K and −1,400 μV/K at 303 K, respectively, which are approximately 7.3 and 6.5 times higher in absolute value than the intrinsic p- and n-type α_Bi–Te at the corresponding temperatures.