A Novel Insensitive High Explosive 3,4‐Bis (Aminofurazano) Furoxan

A novel insensitive high explosive 3,4‐bis (aminofurazano) furoxan (BAFF) was prepared using 3‐amino‐4‐acylchloroximinofurazan (ACOF) as a precursor. The molecular and crystal structures of BAFF were characterized by IR, MS, ¹H NMR, ¹³C NMR, elemental analysis, and single crystal X‐ray diffraction. The single crystal structure of BAFF recrystallized from water is monoclinic, space group P 21/c, and ρ_c=1.745 g cm⁻³, and that recrystallized from ethanol is triclinic, space group P 1, and ρ_c=1.737 g cm⁻³. BAFF has multiple crystal forms. The calculated detonation velocity by BKW code is 8100 m s⁻¹ (ρ=1.795 g cm⁻³, theoretical density calculated by quantum chemistry) and the experimental value is 7177 m s⁻¹ (ρ=1.530 g cm⁻³, charge density). The tested values of impact, friction, and electrostatic spark sensitivity show that BAFF is insensitive.